meso-Tetra(4-carboxyphenyl)porphine
- CasNo:14609-54-2
Product Description
Buy reliable Quality meso-Tetra(4-carboxyphenyl)porphine 14609-54-2 raw material with Honest Price
- Molecular Formula:C48H30N4O8
- Molecular Weight:790.788
- Appearance/Colour:purple powder
- Melting Point:>300 °C
- Refractive Index:1.734
- PSA：205.50000
- Density:1.463 g/cm3
- LogP:5.65900
meso-Tetra(4-carboxyphenyl)porphine(Cas 14609-54-2) Usage
|
Synthesis |
General procedures for the synthesis of porphyrins 1-5A mixture of the appropriate aromatic aldehyde (0.72 mmol) andpyrrole (0.72 mmol) in DMF (15 mL) was placed into a 50 mL threeneckedflask. The mixture was flushed with nitrogen gas for a coupleof minutes and then heated to 100 C for 10 min. P-toluene sulphonicacid (0.72 mmol, dissolved in DMF) was then added to the reactionmixture. The colorless mixture turned red over the next couple of minutesthen heated at 150 C for 1 h. The reaction mixture was thencooled and poured over ice with stirring for 15 min the residue wascollected, dried under vacuum and purified by column chromatographyusing chloroform/hexane (1.5/1) as eluent). |
|
General Description |
Visit our Sensor Applications portal to learn more. |
InChI:InChI=1/C48H30N4O8/c53-45(54)29-9-1-25(2-10-29)41-33-17-19-35(49-33)42(26-3-11-30(12-4-26)46(55)56)37-21-23-39(51-37)44(28-7-15-32(16-8-28)48(59)60)40-24-22-38(52-40)43(36-20-18-34(41)50-36)27-5-13-31(14-6-27)47(57)58/h1-24,49,52H,(H,53,54)(H,55,56)(H,57,58)(H,59,60)/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-
14609-54-2 Relevant articles
Efficient electrocatalytic hydrogen gas evolution by a cobalt-porphyrin-based crystalline polymer
Wu, Yanyu,Veleta, José M.,Tang, Diya,Price, Alex D.,Botez, Cristian E.,Villagrán, Dino
, p. 8801 - 8806 (2018)
Herein, we report a crystalline CoTcPP-b...
Visible-Light Photoreduction of CO2 in a Metal-Organic Framework: Boosting Electron-Hole Separation via Electron Trap States
Xu, Hai-Qun,Hu, Jiahua,Wang, Dengke,Li, Zhaohui,Zhang, Qun,Luo, Yi,Yu, Shu-Hong,Jiang, Hai-Long
, p. 13440 - 13443 (2015)
It is highly desirable to convert CO2 to...
Control of Listeria innocua biofilms by biocompatible photodynamic antifouling chitosan based materials
Castro, Kelly A.D.F.,Moura, Nuno M.M.,Fernandes, Ana,Faustino, Maria A.F.,Sim?es, Mário M.Q.,Cavaleiro, José A.S.,Nakagaki, Shirley,Almeida, Adelaide,Cunha, ?ngela,Silvestre, Armando J.D.,Freire, Carmem S.R.,Pinto, Ricardo J.B.,Neves, Maria da Gra?a P.M.S.
, p. 265 - 276 (2017)
New materials obtained through the incor...
A porphyrin cobalt(II) complex linked to a TiO2/BiVO4 nanocomposite: Alcohol oxidation using nanohybrid materials as a photocatalyst: Via a mechanism approach
Askari, Parvin,Mohebbi, Sajjad
, p. 1715 - 1724 (2018)
Herein, a new nanohybrid catalyst was sy...
A zinc sulfide-supported iron tetrakis (4-carboxyl phenyl) porphyrin catalyst for aerobic oxidation of cyclohexane
Jiang, Yue-Xiu,Su, Tong-Ming,Qin, Zu-Zeng,Huang, Guan
, p. 24788 - 24794 (2015)
Zinc sulfide-supported iron tetrakis (4-...
Synthesis and photocytotoxic activity of new chlorin-polyamine conjugates
Garcia, Guillaume,Sol, Vincent,Lamarche, Francois,Granet, Robert,Guilloton, Michel,Champavier, Yves,Krausz, Pierre
, p. 3188 - 3192 (2006)
This paper reports the synthesis of new ...
Facile synthesis, photophysical and electrochemical redox properties of octa- and tetracarboxamidophenylporphyrins and the first example of amido-imidol tautomerism in porphyrins
Yadav, Pinky,Sankar, Muniappan
, p. 651 - 657 (2017)
5,10,15,20-tetrakis(4′-carboxamidophenyl...
Modulating the Acidic and Basic Site Concentration of Metal-Organic Framework Derivatives to Promote the Carbon Dioxide Epoxidation Reaction
Ji, Jinhua,Liu, Hao,Chen, Zewei,Fu, Yajun,Yang, Weijun,Yin, Shuang-Feng
, p. 11102 - 11109 (2021)
Metal-organic framework (MOF) is an idea...
N-confused porphyrin possessing glucamine-appendants: Aggregation and acid/base properties in aqueous media
Ikawa, Yoshiya,Ogawa, Hiroaki,Harada, Hiroyuki,Furuta, Hiroyuki
, p. 6394 - 6397 (2008)
A water-soluble derivative of N-confused...
Straightforward synthesis of a porous chromium-based porphyrinic metal-organic framework for visible-light triggered selective aerobic oxidation of benzyl alcohol to benzaldehyde
Daliran, Saba,García, Hermenegildo,Khajeh, Mostafa,Luque, Rafael,Oudi, Sara,Oveisi, Ali Reza,Sen, Unal
, (2021)
Among MOFs, chromium-based metal–organic...
In situ self-assembly of zirconium metal-organic frameworks onto ultrathin carbon nitride for enhanced visible light-driven conversion of CO2 to CO
Guo, Haiwei,Wan, Shipeng,Wang, Yanan,Zeng, Yiqing,Zhang, Shule,Zhen, Wenlong,Zhong, Qin
, p. 6034 - 6040 (2020)
A series of Zr-porphyrin metal-organic f...
Ruthenium-porphyrin conjugates with cytotoxic and phototoxic antitumor activity
Gianferrara, Teresa,Bergamo, Alberta,Bratsos, Ioannis,Milani, Barbara,Spagnul, Cinzia,Sava, Gianni,Alessio, Enzo
, p. 4678 - 4690 (2010)
We report here two novel extended-arms p...
Extra Unsaturated Metal Centers of Zirconium-Based MOFs: a Facile Approach towards Increasing CO2 Uptake Capacity at Low Pressure
Li, Zhong,Li, Xue,Chen, Chong,Zhou, Lijin,Guo, Qirui,Yuan, Dashui,Wan, Hui,Ding, Jing,Guan, Guofeng
, p. 194 - 202 (2018)
Developing adsorption materials to captu...
Synthesis of Novel Porphyrin Derivatives with Mesogenic Properties
Zhang, Xiaoyuan,Zhu, Biaobiao,Zhou, Li,Liu, Ping,Deng, Wenji
, p. 2730 - 2739 (2015)
Two novel porphyrin derivatives, 5,10,15...
From Metal–Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media
Jiao, Long,Wan, Gang,Zhang, Rui,Zhou, Hua,Yu, Shu-Hong,Jiang, Hai-Long
, p. 8525 - 8529 (2018)
It remains highly desired but a great ch...
Mg–Al layered double hydroxide intercalated with manganese(III) 5,10,15,20-tetrakis(4-benzoate)porphyrinacetate as a highly reusable catalyst for epoxidation
Bagherzadeh, Mojtaba,Mesbahi, Elnaz
, (2019)
The preparation and characterization are...
Metalloporphyrins as chemical shift reagents: the unambiguous NMR characterization of the cis- and trans-isomers of meso-(bis)-4′-pyridyl-(bis)-4′-carboxymethylphenylporphyrins
Gianferrara, Teresa,Giust, Davide,Bratsos, Ioannis,Alessio, Enzo
, p. 5006 - 5013 (2007)
The condensation of pyrrole with 4-pyrid...
Visible light production of superoxide anion with MCarboxyphenylporphyrins (M = H, Fe, Co, Ni, Cu, and Zn) free and anchored on TiO2: EPR characterization
Granados-Oliveros, Gilma,Páez-Mozo, Edgar Alberto,Martínez Ortega, Fernando,Piccinato, Marileneturini,Silva, Fausto Neves,Guedes, Carmen Luísa Barbosa,Di Mauro, Eduardo,Costa, Marcello Ferreira Da,Ota, André Tsutomu
, p. 79 - 85 (2011)
Metal carboxyphenylporphyrins: TcPPM, M ...
Nanoscale Synthesis of Two Porphyrin-Based MOFs with Gallium and Indium
Rhauderwiek, Timo,Waitschat, Steve,Wuttke, Stefan,Reinsch, Helge,Bein, Thomas,Stock, Norbert
, p. 5312 - 5319 (2016)
Two porphyrin-based metal-organic framew...
A simple strategy for engineering heterostructures of Au nanoparticle-loaded metal-organic framework nanosheets to achieve plasmon-enhanced photocatalytic CO2 conversion under visible light
Chen, Liyong,Wang, Yanxin,Yu, Fengyang,Shen, Xiaoshuang,Duan, Chunying
, p. 11355 - 11361 (2019)
Carbon dioxide selectively concentrated ...
Porphyrinic Metal-Organic Framework Catalyzed Heck-Reaction: Fluorescence "turn-On" Sensing of Cu(II) Ion
Chen, Yu-Zhen,Jiang, Hai-Long
, p. 6698 - 6704 (2016)
It is of great importance for the highly...
Redox-responsive porphyrin-based polysilsesquioxane nanoparticles for photodynamic therapy of cancer cells
Vega, Daniel L.,Lodge, Patrick,Vivero-Escoto, Juan L.
, (2016)
The development of stimulus-responsive p...
MOF/PEDOT/HPMo-based polycomponent hierarchical hollow micro-vesicles for high performance flexible supercapacitors
Wang, Bing,Liu, Shuo,Liu, Lin,Song, Wen-Wei,Zhang, Yue,Wang, Shi-Ming,Han, Zheng-Bo
, p. 2948 - 2958 (2021)
Metal-organic frameworks (MOFs) are prom...
An Efficient Catalyst Based on a Metal Metalloporphyrinic Framework for Highly Selective Oxidation
Zhang, Weijie,Jiang, Pingping,Wang, Ying,Zhang, Jian,Zhang, Pingbo
, p. 589 - 595 (2015)
An efficient metal-organic framework cat...
Metal–Organic Frameworks for the Exploitation of Distance between Active Sites in Efficient Photocatalysis
Deng, Hexiang,Gong, Xuan,Jiang, Zhuo,Lu, Lingxiang,Shu, Yufei,Wang, Chao,Xu, Xiaohui
, p. 5326 - 5331 (2020)
Discoveries of the accurate spatial arra...
Photodynamic effect of 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin and (Zn2+ and Sn4+) derivatives against Leishmania spp in the promastigote stage: experimental and DFT study
Espitia-Almeida, Fabián,Díaz-Uribe, Carlos,Vallejo, William,Pe?a, Orlando,Gómez-Camargo, Doris,Bohórquez, Arnold R. Romero,Zarate, Ximena,Schott, Eduardo
, p. 4817 - 4829 (2021)
In this work, we synthesized the meso-(a...
Metal–Organic Framework-Derived FeCo-N-Doped Hollow Porous Carbon Nanocubes for Electrocatalysis in Acidic and Alkaline Media
Fang, Xinzuo,Jiao, Long,Yu, Shu-Hong,Jiang, Hai-Long
, p. 3019 - 3024 (2017)
Metal–organic frameworks (MOFs) are idea...
Rapid and specific luminescence sensing of Cu(II) ions with a porphyrinic metal-organic framework
Li, Linnan,Shen, Sensen,Lin, Ruoyun,Bai, Yu,Liu, Huwei
, p. 9986 - 9989 (2017)
We herein present a porphyrinic metal-or...
Enhanced Photodynamic Therapy by Reduced Levels of Intracellular Glutathione Obtained By Employing a Nano-MOF with CuII as the Active Center
Zhang, Wei,Lu, Jun,Gao, Xiaonan,Li, Ping,Zhang, Wen,Ma, Yu,Wang, Hui,Tang, Bo
, p. 4891 - 4896 (2018)
In photodynamic therapy (PDT), the level...
A novel drug-drug nanohybrid for the self-delivery of porphyrin and: Cis-platinum
Shan, Changfu,Ru, Jiaxi,Zhang, Meina,Cao, Jing,Liu, Weisheng,Guo, Huichen,Tang, Yu
, p. 37003 - 37008 (2019)
The thriving development of nanotechnolo...
Neutral Porphyrin Derivative Exerts Anticancer Activity by Targeting Cellular Topoisomerase i (Top1) and Promotes Apoptotic Cell Death without Stabilizing Top1-DNA Cleavage Complexes
Das, Subhendu K.,Ghosh, Arijit,Paul Chowdhuri, Srijita,Halder, Nyancy,Rehman, Ishita,Sengupta, Souvik,Sahoo, Krushna Chandra,Rath, Harapriya,Das, Benu Brata
, p. 804 - 817 (2018)
Camptothecin (CPT) selectively traps top...
Conformational-Switch Based Strategy Triggered by [18] π Heteroannulenes toward Reduction of Alpha Synuclein Oligomer Toxicity
Chakraborty, Ritobrita,Sahoo, Sumit,Halder, Nyancy,Rath, Harapriya,Chattopadhyay, Krishnananda
, p. 573 - 587 (2019)
A water-soluble meso-carboxy aryl substi...
Porphyrin derivatives as potent and selective blockers of neuronal Kv1 channels
Daly,Al-Sabi,Kinsella,Nolan,Dolly
, p. 1066 - 1069 (2015)
Selective inhibitors of voltage-activate...
Porphyrin Antennas on Carbon Nanodots: Excited State Energy and Electron Transduction
Arcudi, Francesca,Strauss, Volker,?or?evi?, Luka,Cadranel, Alejandro,Guldi, Dirk M.,Prato, Maurizio
, p. 12097 - 12101 (2017)
We report the synthesis and electron don...
Synthesis of magnetite-porphyrin nanocomposite and its application as a novel magnetic adsorbent for removing heavy cations
Bakhshayesh, Sara,Dehghani, Hossein
, p. 2614 - 2624 (2013)
Magnetite-porphyrin nanocomposite (MPNC)...
Cis -Decalin oxidation as a stereochemical probe of in-MOF versus on-MOF catalysis
Cardenal, Ashley D.,Jeong Park, Hye,Chalker, Cody J.,Ortiz, Kacey G.,Powers, David C.
, p. 7377 - 7380 (2017)
Development of catalyst-controlled C-H h...
A spectroscopic and molecular docking study of interactions of tetracarboxyphenyl porphyrin and chlorin e6 with bovine serum albumin
Vicente-Escobar, Jonathan Osiris,García-Sánchez, Miguel A.,González,Cipagauta-Díaz,Estrella González
, p. 4501 - 4515 (2021)
Abstract: In order to use tetrapyrrolic ...
A stable and highly selective metalloporphyrin based framework for the catalytic oxidation of cyclohexene
Feng, Pingyun,Li, Fengyan,Xia, Zhinan,Xu, Lin
, p. 11157 - 11162 (2020)
A new metalloporphyrin framework of moly...
Photocatalytic activity of nanohybrid Co-TCPP@TiO2/WO3 in aerobic oxidation of alcohols under visible light
Safaei, Elham,Mohebbi, Sajjad
, p. 3933 - 3946 (2016)
Here the photocatalytic performance acti...
Electrostatic core shielding in dendritic polyglutamic porphyrins
Vinogradov, Sergei A.,Wilson, David F.
, p. 2456 - 2461 (2000)
Polyglutamic dendritic porphyrins of the...
Conjugates of platinum nanoparticles with gallium tetra - (4-Carboxyphenyl) porphyrin and their use in photodynamic antimicrobial chemotherapy when in solution or embedded in electrospun fiber
Managa, Muthumuni,Antunes, Edith,Nyokong, Tebello
, p. 94 - 101 (2014)
The conjugation of Pt nanoparticles with...
Syntheses and energy transfer in multiporphyrinic arrays self-assembled with hydrogen-bonding recognition groups and comparison with covalent steroidal models
Balaban, Teodor Silviu,Berova, Nina,Drain, Charles Michael,Hauschild, Robert,Huang, Xuefei,Kalt, Heinz,Lebedkin, Sergei,Lehn, Jean-Marie,Nifaitis, Fotis,Pescitelli, Gennaro,Prokhorenko, Valentyn I.,Riedel, Gernot,Smeureanu, Gabriela,Zeller, Joachim
, p. 8411 - 8427 (2007)
A number of new porphyrins equipped with...
DNA photocleavage by porphyrin-polyamine conjugates
Garcia, Guillaume,Sarrazy, Vincent,Sol, Vincent,Morvan, Caroline Le,Granet, Robert,Alves, Sandra,Krausz, Pierre
, p. 767 - 776 (2009)
A series of polyamine-porphyrin conjugat...
Immobilization of Rh(i) precursor in a porphyrin metal-organic framework - turning on the catalytic activity
Bury, Wojciech,Janeta, Mateusz,Siczek, Mi?osz,Szczepkowska, Anna M.,Trzeciak, Anna M.,Tylus, W?odzimierz
, p. 9051 - 9058 (2021)
Two model porphyrin metal-organic framew...
Visible light superoxide radical anion generation by tetra(4-carboxyphenyl) porphyrin/TiO2: EPR characterization
Diaz-Uribe, Carlos E.,Daza, Martha C.,Martínez, Fernando,Páez-Mozo, Edgar A.,Guedes, Carmen L.B.,Di Mauro, Eduardo
, p. 172 - 178 (2010)
The generation of superoxide radical ani...
Selective oxidation of aromatic sulfide catalyzed by an artificial metalloenzyme: New activity of hemozymes
Ricoux, Remy,Allard, Mathieu,Dubuc, Roger,Dupont, Claude,Marechal, Jean-Didier,Mahy, Jean-Pierre
, p. 3208 - 3211 (2009)
Two new artificial hemoproteins or "hemo...
Porphyrin supramolecular arrays formed by weakly interacting meso-functional groups on Au(111)
Sánchez-Mu?oz, Esteban,Gárate-Morales, José L.,Sandoval-Lira, Jacinto,Hernández-Pérez, Julio M.,Aguilar-Sánchez, Rocío
, (2019)
The formation of a binary porphyrinic se...
Synthesis and catalytic behavior of tetrakis(4-carboxyphenyl) porphyrin-periodic mesoporous organosilica
Jeong, Eun-Young,Burri, Abhishek,Lee, Seung-Yeop,Park, Sang-Eon
, p. 10869 - 10875 (2010)
The periodic mesoporous organosilica hav...
A large π-conjugated tetrakis (4-carboxyphenyl) porphyrin anode enables high specific capacity and superior cycling stability in lithium-ion batteries
Cui, Guanglei,Du, Xiaofan,Liu, Hao,Luo, Ting,Wu, Han,Xu, Hai,Yang, Jinfeng,Zhang, Jianjun,Zhang, Jinning,Zhang, Min
, p. 11370 - 11373 (2019)
We demonstrated a novel single molecule-...
Metal-Organic Framework-Templated Porous Carbon for Highly Efficient Catalysis: The Critical Role of Pyrrolic Nitrogen Species
Huang, Gang,Yang, Li,Ma, Xiao,Jiang, Jun,Yu, Shu-Hong,Jiang, Hai-Long
, p. 3470 - 3477 (2016)
Metal-free catalysts are of great import...
Fabrication and application of copper metal–organic frameworks as nanocarriers for pH-responsive anticancer drug delivery
Gharehdaghi, Zahra,Molaabasi, Fatemeh,Naghib, Seyed Morteza,Rahimi, Rahmatollah
, (2022/01/11)
Copper-based metal?organic frameworks (C...
Surface decorated magnetic nanoparticles with Mn-porphyrin as an effective catalyst for oxidation of sulfides
Shokoohi, Saeedeh,Rayati, Saeed
, p. 8 - 18 (2021/07/19)
Mn-porphyrin complex was anchored coordi...
Metalloporphyrin-Decorated Titanium Dioxide Nanosheets for Efficient Photocatalytic Carbon Dioxide Reduction
Li, Ang,Chen, Siyuan,Yang, Fucheng,Gao, Hongyi,Dong, Cheng,Wang, Ge
, p. 18337 - 18346 (2021/11/23)
In photocatalysis, the most efficient wa...
14609-54-2 Process route
-
-
109-97-7,30604-81-0
pyrrole
-
-
1571-08-0
methyl 4-formylbenzoate
-
-
14609-54-2
tetrakis(4-carboxyphenyl)porphyrin
| Conditions | Yield |
|---|---|
|
pyrrole; methyl 4-formylbenzoate;
With
boron trifluoride diethyl etherate;
In
dichloromethane;
at 20 ℃;
for 1.5h;
Darkness;
With
chloranil;
In
dichloromethane;
With
sodium hydroxide;
|
35% |
|
pyrrole; methyl 4-formylbenzoate;
With
propionic acid;
at 160 ℃;
for 12h;
With
potassium hydroxide;
In
tetrahydrofuran; methanol; water;
at 80 ℃;
for 12h;
|
|
|
pyrrole; methyl 4-formylbenzoate;
With
propionic acid;
at 140 ℃;
for 12h;
With
potassium hydroxide;
In
tetrahydrofuran; methanol; water;
at 80 ℃;
for 12h;
|
|
|
pyrrole; methyl 4-formylbenzoate;
With
propionic acid;
In
dimethyl sulfoxide;
at 130 ℃;
for 2h;
With
potassium hydroxide;
In
tetrahydrofuran; methanol;
at 80 ℃;
for 12h;
|
-
-
1571-08-0
methyl 4-formylbenzoate
-
-
14609-54-2
tetrakis(4-carboxyphenyl)porphyrin
| Conditions | Yield |
|---|---|
|
Multi-step reaction with 2 steps
1: propionic acid / 1 h / 80 - 140 °C
2: potassium hydroxide / tetrahydrofuran / 24 h / Reflux
With
propionic acid; potassium hydroxide;
In
tetrahydrofuran;
|
|
|
Multi-step reaction with 2 steps
1: propionic acid / 1.5 h / 140 °C
2: potassium hydroxide / tetrahydrofuran; water / 48 h / 66 °C
With
propionic acid; potassium hydroxide;
In
tetrahydrofuran; water;
|
|
|
Multi-step reaction with 2 steps
1: propionic acid / 12 h / Reflux
2: sodium hydroxide / water; tetrahydrofuran; methanol / 12 h / Reflux
With
propionic acid; sodium hydroxide;
In
tetrahydrofuran; methanol; water;
|
|
|
Multi-step reaction with 2 steps
1: propionic acid / 140 °C
2: potassium hydroxide / tetrahydrofuran; methanol; water / 12 h / Reflux
With
propionic acid; potassium hydroxide;
In
tetrahydrofuran; methanol; water;
|
|
|
Multi-step reaction with 2 steps
1: propionic acid / 12 h / Reflux; Inert atmosphere
2: potassium hydroxide / tetrahydrofuran; methanol; water / 16 h / Reflux
With
propionic acid; potassium hydroxide;
In
tetrahydrofuran; methanol; water;
|
|
|
Multi-step reaction with 2 steps
1: propionic acid / 12 h / 140 °C / Darkness
2: potassium hydroxide / tetrahydrofuran; methanol; water / 12 h / 85 °C
With
propionic acid; potassium hydroxide;
In
tetrahydrofuran; methanol; water;
|
|
|
Multi-step reaction with 2 steps
1: 12 h / Schlenk technique; Inert atmosphere; Reflux
2: potassium hydroxide / tetrahydrofuran; methanol / 12 h / Reflux
With
potassium hydroxide;
In
tetrahydrofuran; methanol;
|
|
|
Multi-step reaction with 2 steps
1: propionic acid / 12 h / Reflux; Darkness
2: potassium hydroxide / tetrahydrofuran; methanol; water / 12 h / Reflux
With
potassium hydroxide;
In
tetrahydrofuran; methanol; water; propionic acid;
|
|
|
Multi-step reaction with 2 steps
1: propionic acid / 12 h / 120 °C
2: water; potassium hydroxide / tetrahydrofuran; methanol / 12 h / 120 °C
With
water; propionic acid; potassium hydroxide;
In
tetrahydrofuran; methanol;
|
|
|
Multi-step reaction with 2 steps
1: propionic acid / 12 h / Reflux
2: sodium hydroxide / tetrahydrofuran; methanol / 12 h / Reflux
With
sodium hydroxide;
In
tetrahydrofuran; methanol; propionic acid;
|
|
|
Multi-step reaction with 2 steps
1: propionic acid / 10 h / 150 °C / Inert atmosphere
2: potassium hydroxide / tetrahydrofuran; water; methanol / 24 h / 80 °C
With
propionic acid; potassium hydroxide;
In
tetrahydrofuran; methanol; water;
|
|
|
Multi-step reaction with 2 steps
1.1: 80 °C
1.2: 1 h / 140 °C
2.1: hydrogenchloride / trifluoroacetic acid / 36 h / 85 °C
With
hydrogenchloride;
In
trifluoroacetic acid;
|
14609-54-2 Upstream products
-
109-97-7
pyrrole
-
619-66-9
4-Carboxybenzaldehyde
-
22112-83-0
5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin
-
14609-51-9
5,10,15,20-tetrakis(4-cyanophenyl)porphirin
14609-54-2 Downstream products
-
22112-83-0
5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin
-
74681-89-3
10-(4-hexadecyloxycarbonylphenyl)-5,15,20-tris<4-carboxyphenyl>-21H,23H-phorphine trihydrate
-
139328-06-6
5,10,15,20-tetrakis<4-<4-(chloromethyl)benzyloxycarbonyl>phenyl>porphyrin